Question 22: What preventative maintenance program is applied to safety instrumented systems on a steam methane reformer that are Safety Integrity Level (SIL) rated?

Safety instrumented systems (SIS), as defined by ANSI/ISA-84.00.01-2004 Part 1(IEC-61511-1 Mod), are required to have components functionally tested and/or replaced/ refurbished under preventative maintenance (PM) to provide the reliability required to have a Safety Integrity Level (SIL) rating. SIL-rated safety systems are often required when a greater degree of protection layers is required then that offered by standard design.

Question 21: High pressure strippers are an option for controlling VOCs in process condensate and managing export steam quality in a steam methane reformer hydrogen plant. What types of pH controls are being used?

Most hydrogen plants take the process condensate, send it to a deaerator to clean it up, and then reuse that condensate while mixing it with some boiler feedwater internally. There are configurations that have high pressure strippers where they will bring in some steam and do some initial stripping.

Question 18: What are the economic incentives to justify upgrading reactor internals? What techniques have been utilized to assess the performance of existing reactor internals?

The primary incentive is catalyst life and the ability to meet turnaround intervals. Gas and liquid distribution improvement results in increased catalyst performance and potentially longer catalyst life. Reactor internal upgrades may consist of quench decks, mixing chambers, and improved liquid distributor trays.

Question 16: What is the commercial experience on the use of H2 membranes in hydrotreaters or hydrocrackers for H2 recovery? What is a reasonable membrane life given the sensitivity to fouling and temperature changes?

At the Denver Refinery, we have a few hydrogen separation membranes. We call them our hydrogen purification unit. Our #3 HDS, which is currently our ULSD unit, was previously a gas oil hydrotreater until we revamped it in 2006. So, the HPUs (hydrogen purification units) were in consistent service from 1990 to 2006.